Bretherick's Handbook of Reactive Chemical Hazards, Seventh by Peter Urben

By Peter Urben

Bretherick's guide of Reactive Chemical dangers is extensively considered as the reference paintings during this box - an meeting of all mentioned hazards resembling explosion, fireplace, poisonous or high-energy occasions that consequence from chemical reactions long gone off course, with broad referencing to the first literature. it really is designed to enhance defense in laboratories that practice chemical synthesis and common examine, in addition to chemical production crops. Entries are ordered through empirical formulation and listed less than either name(s) and Chemical Abstracts Registry Numbers. This two-volume compendium makes a speciality of reactivity dangers of chemical compounds, by myself and together; toxicity dangers are just incorporated for unforeseen reactions giving unstable poisons.The 2-volume set is accessible on an introductory cost of $320/?270/??185 till Jan 2007. Will then revert to the record cost of $395/?330/??230. Order your reproduction on the introductory cost now. * expect, stay away from, and keep watch over reactivity risk with this most modern version of the prime consultant * Covers each chemical with documented info on reactive risks; greater than 5,000 entries on unmarried components or compounds, and 5,000 entries at the interactions among or extra compounds * comprises 5 years of latest studies, new references to the first literature, and amplification to latest entries* hyperlinks related compounds or incidents that aren't evidently similar

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Arbeitsschutz, 1966, 156—157 Lamoroux, A. , Me´m. Poudres, 1957, 39, 435—445 Hamstead, A. C. , Ind. Eng. , 1948, 40, 756 MCA Case History No. , Ind. Eng. , Prod. Res. , 1976, 15, 150 Wendon, G. , Ind. Eng. , Prod. Res. , Ind. Eng. , Prod. Res. , 1977, 16, 112 Archer, W. , Paper 47, 1—11, presented at Corrosion/78, Houston, March 6—10, 1978 25. Anon. Univ. Safety Assoc. Newsletter, 1982, (16), 5 26. Stull, 1977, 22 27. , J. 67/89 Heating aluminium powder with carbon tetrachloride, chloromethane or carbon tetrachloride—chloroform mixtures in closed systems to 152 C may cause an explosion, particularly if traces of aluminium chloride are present [1].

Hydrogen produced by alkaline attack on the ladder generated arsine, which poisoned the three workers involved. Barium peroxide See Barium peroxide: Metals Bismuth Mellor, 1947, Vol. 9, 626 The finely divided mixture of metals produced by hydrogen reduction of co-precipitated bismuth and aluminium hydroxides is pyrophoric. Butanol 1. Luberoff, B. , 1964 2. Bogart, M. J. , Chem. Eng. , 1988, (2), 82 Butanol, used as a solvent in an autoclave preparation at around 100 C, severely attacked the aluminium gasket, liberating hydrogen which caused a sharp rise in pressure.

Derivatives of this compound are effective methyleneating agents for ketones. See Halocarbons, below Diethyl ether Murdock, T. D. Thesis, Univ. N. Dakota, 1977 (Diss. Abs. B, 1978, 39, 1291) The aluminium—solvent slurry produced by metal atom/solvent co-condensation at —196 C is so reactive that oxygen is abstracted from the solvent ether as the mixture is allowed to melt. Hydrocarbon solvents are more suitable (but halocarbon solvents would react explosively). 25 Disulfur dibromide See Disulfur dibromide: Metals Drain cleaner, Cola 1.

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