Catalysts for Fine Chemical Synthesis: Metal Catalysed by Stanley M. Roberts, Ivan V. Kozhevnikov, Eric Derouane(eds.)

By Stanley M. Roberts, Ivan V. Kozhevnikov, Eric Derouane(eds.)

The chemist has an enormous variety of high-tech catalysts to take advantage of whilst operating in fine chemical synthesis however the catalysts are normally not easy to take advantage of and require either time, ability and adventure to deal with adequately. The Catalysts for tremendous Chemical Synthesis series contains demonstrated and verified methods which provide a different variety assets for chemists who paintings in natural chemistry.

"... of serious worth to artificial natural chemists..." (The Chemists, summer time 2003)

quantity three within the sequence specializes in catalysts for carbon-carbon bond formation and offers sensible  and detailed protocols on tips to use subtle catalysts through the "inventors" and "developers" who created them. The combination of protocols and overview commentaries is helping the reader to simply and quickly understand and use the recent high-tech catalysts.Content:
Chapter 1 issues of commercial tremendous Chemical Synthesis (pages 1–12): Mark W. Hooper
Chapter 2 Alkylation and Allylation adjoining to a Carbonyl workforce (pages 13–33): Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani, Michael North, Jose A. Fuentes, Barry Lygo and Benjamin I. Andrews
Chapter three uneven Alkylation or Amination of Allylic Esters (pages 35–57): Maria Zablocka, Marek Koprowski, Jean?Pierre Majoral, Mathieu Achard, Gerard Buono, Jerome Bayardon, Denis Sinou, Matthias Lotz, Gernot Kramer, Katja Tappe, Paul Knochel, Pierluigi Barbaro, Claudio Bianchini, Giuliano Giambastiani and Antonio Togni
Chapter four Suzuki Coupling Reactions (pages 59–90): Ana S. Abreu, Paula M. T. Ferreira, Maria?Joao R. P. Queiroz, Jie Wu, Lisha Wang, Reza Fathi, Zhen Yang, Ramon E. Huertas, John A. Soderquist, Tatsuo Ishiyama, Norio Miyaura, Bin Tao, David W. Boykin, Colin Baillie, Lijin Xu, Jianliang Xiao, Matthew L. Clarke, J. Derek Woollins, Nicholas Marion, Oscar Navarro, Roy A. Kelly and Steven P. Nolan
Chapter five Heck Coupling Reactions (pages 91–112): Peter Nilsson, Mats Larhed, Lijin Xu, Jun Mo, Jianliang Xiao, Tim G. Kilroy, Yvonne M. Malone and Patrick J. Guiry
Chapter 6 Sonogashira Coupling Reactions (pages 113–125): Anupama Datta, Herbert Plenio, Chih?An Lin and Fen?Tair Luo
Chapter 7 Cross?Coupling Reactions (pages 127–153): Jun Terao, Nobuaki Kambe, Luis A. Sarandeses, Jose Perez Sestelo, Bryan A. Frieman, Bruce H. Lipshutz, John Mancuso, Masahiro Yoshida and Mark Lautens
Chapter eight Regioselective or uneven 1,2?Addition to Aldehydes (pages 155–168): Kui?Thong Tan, Shu?Sin Chng, Hin?Soon Cheng, Teck?Peng Loh, Jens Rudolph, Carsten Bolm, Marco Lombardo, Sebastiano Licciulli, Stefano Morganti and Claudio Trombini
Chapter nine Olefin Metathesis Reactions (pages 169–180): Syuzanna Harutyunyan, Anna Michrowska, Karol Grela, Stephen J. Connon, Aideen M. Dunne, Siegfried Blechert, G. Bhaskar and B. Venkateswara Rao
Chapter 10 Cyclisation Reactions (pages 181–200): Jaime Blanco?Urgoiti, Gema Dominguez, Javier Perez?Castells, Ligang Zhao, Xiyan Lu, Minsheng He, Aiwen Lei, Xumu Zhang, Hiroshi Shinokubo, Koichiro Oshima, Antonio Rosales, Juan M. Cuerva and Enrique Oltra
Chapter eleven uneven Aldol and Michael Reactions (pages 201–223): Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai, Zhuo Tang, Liu?Zhu Gong, Ai?Qiao Mi, Yao?Zhong Jiang, Masahito Watanabe, Kunihiko Murata and Takao Ikariya
Chapter 12 Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions (pages 225–250): Bernhard Breit, Martin Wills, Simon W. Breeden, Stefania Cserepi?Szucs, Jozsef Bakos, C. Ramesh, Y. Kubota, Y. Sugi, Tomoko Matsuda, Tadao Harada, Toru Nagasawa and Kaoru Nakamura

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Additional info for Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions, Volume 3

Sample text

Kitchen and bathroom surfaces, co-polymerises with other monomers, and is used in paints and coatings. [8] It involves a two-step process: a liquid phase methoxy-carbonylation followed by a gas phase condensation. CO þ C2 H4 þ MeOH ! CH3 CH2 CO2 CH3 CH3 CH2 CO2 CH3 þ CH2 O ! CH2 CðCH3 ÞCO2 CH3 The first step involves a homogeneous palladium-catalyst based on a chelating bisphosphine (3). Some general features of the process are: 12      METAL CATALYSED CARBON-CARBON BOND-FORMING REACTIONS 1 kg of catalyst will produce 200 tonnes of methyl propionate.

References . . . . . . . . . . . . . . . . . . . . . . . . . . ASYMMETRIC PHASE-TRANSFER CATALYSED ALKYLATION OF GLYCINE IMINES USING CINCHONA KETONES VIA CARBON-HYDROGEN BOND CLEAVAGE .... 14 14 .... 16 . . 17 18 19 21 . . . . . . COPPER-SALEN COMPLEX AS A PHASE TRANSFER CATALYST 21 22 23 24 26 27 ALKALOID DERIVED QUATERNARY AMMONIUM SALTS BARRY LYGO and BENJAMIN I. ANDREWS . . . . . . . . . . . . . . . . 2]octane bromide .

4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . ASYMMETRIC PHASE-TRANSFER CATALYSED ALKYLATION OF GLYCINE IMINES USING CINCHONA KETONES VIA CARBON-HYDROGEN BOND CLEAVAGE .... 14 14 .... 16 . . 17 18 19 21 . . . . . . COPPER-SALEN COMPLEX AS A PHASE TRANSFER CATALYST 21 22 23 24 26 27 ALKALOID DERIVED QUATERNARY AMMONIUM SALTS BARRY LYGO and BENJAMIN I. ANDREWS .

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