By Lomova, Gennady Zaikov
The publication is dedicated to kinetics and thermodynamics of the strategies with participation of a few organic compounds and their artificial analogues. features in their performing as version enzymes, molecular receptors, photograph sensitizers, pharmocophores, and biopharmaceutical compounds are into consideration. Quantitative features of move of cations, anions and small natural molecules, fermentative catalysis, diffusion of the drug molecular via organic membranes are came upon. Mechanisms of the approaches are mentioned. organic task of studied compounds is evaluated. Bio-damages of fabrics in addition to adhesions of microorganisms on fabrics floor are investigated.
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Thus, in the interaction of hydrazine with anhydrides of aromatic dicarboxylic acids symmetric hydrazides are formed with the increase of the initial five-membered cycle to the six-membered cycle (Scheme 29) [49]. In the case of bacteriopurpurine, this could lead to the formation of hydrazide with six100a or seven-membered 100b cycles. The use of 2D heteronuclear resonance and the study Synthetic and Natural Bacteriochlorins: Synthesis, Properties and Applications 29 O 0 0 HO NH NH N O O CO2Me HN N HN N N CO2Me 96 C A OH 0 H NH N B N HN N HN N NH O CO2Me O CO2Me 97 95 D E CN OH NC NH N N N Zn N HN N O CO2Me N O CO2Me 98 A: NH2SO3H/NaClO2, THP, 2-methyl-2-butene; B: t-BuNH2*BH3, CH2Cl2; C: AcOH/EDC*HCl/DMAP, CH2Cl2; D: malonic acid dinitrile, Et3N, THP; E: Zn(OAc)2, CH2Cl2/CH3OH Scheme 27 Chemical transformations of 3-formyl-3-deacetylbacteriopyropheophorbide.
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