By G. Charlot
Read Online or Download Chemical Reactions in Solvents and Melts PDF
Similar chemical books
Written via an engineer for engineers, this publication is either education guide and on-going reference, bringing jointly the entire various aspects of the complicated tactics that needs to be in position to lessen the chance to humans, plant and the surroundings from fires, explosions, vapour releases and oil spills. totally compliant with foreign regulatory standards, rather compact yet complete in its insurance, engineers, protection execs and anxious corporation administration will purchase this ebook to capitalize at the author's life-long expertise.
This booklet offers large and complete info to researchers and academicians who're drawn to radionuclide illness, its resources and environmental impression. it's also priceless for graduate and undergraduate scholars focusing on radioactive-waste disposal and its effect on usual in addition to artifical environments.
- Information and communications: challenges for the chemical sciences in the 21st century
- The Vibrational Spectroscopy of Polymers (Cambridge Solid State Science Series)
- Working with Ion-Selective Electrodes: Chemical Laboratory Practice
- Enzymes for Pulp and Paper Processing
- Solvent Effects and Chemical Reactivity
Extra resources for Chemical Reactions in Solvents and Melts
Sample text
V (2 - x) 7 9 j j (1957)]. 2a CRS 42 CHEMICAL REACTIONS IN SOLVENTS AND MELTS Solvent pH i 6 , Solvent 7 8 - ^^/ 9 n 10 jr 11 12 13 - j S ^ ^ ml HCI FIGS. 22-24. Werner, / . Am. Chem. Soc. 50, 2367 (1928)]. The pH of half-neutralization depends on the nature of the titrating acid; the pH for a given excess of titrant depends onlthe nature of titrated base. 3. Titration of weak bases by a weak acid (or inversely): see the case where the solvent does not interact. 4. Titration of a metallic salt MA by an acid HA'.
It is the same for aliphatic amines and substituted pyridines. It is impossible at present to relate the two phenomena. Effect of Association due to Hydrogen Bonding on Acid-Base Reactions We are, most of all, interested to know how hydrogen bonds can affect acid-base reactions and how to take them into account. We suppose that B and HA, when placed together, react according to an acid-base reaction. If the reacting species are associated by hydrogen bonding, their reactivity with respect to proton transfer is modified.
CALDIN, Quart. Revs. 7, 255 (1953). COULSON, Research (London) 10, 149 (1957). MCCLELLAN, (a) The Hydrogen Bond, Freeman, 1960 (2250 references). (b) Effect of condensation and of association by hydrogen bonding on acid-base reactions. 5. HARTLEY, / . Chem. Soc. 199 (1931). 6. WALDEN and E. BIRR, Z. Physik. Chem. A163, 263, 321 (1932). 7. V . K . DOWNES, / . Am. Chem. Soc. 55, 1840 (1933). 8. HETZER, / . Res. Nat. Bur. Stand. 46, 496 (1951). 9. SINGLETERRY, / . Phys. Chem. 56, 604 (1952). 10. , / .