Chemical Reactions in Solvents and Melts by G. Charlot

By G. Charlot

Show description

Read Online or Download Chemical Reactions in Solvents and Melts PDF

Similar chemical books

Handbook of Fire and Explosion Protection Engineering Principles. For Oil, Gas, Chemical and Related Facilities

Written via an engineer for engineers, this publication is either education guide and on-going reference, bringing jointly the entire various aspects of the complicated tactics that needs to be in position to lessen the chance to humans, plant and the surroundings from fires, explosions, vapour releases and oil spills. totally compliant with foreign regulatory standards, rather compact yet complete in its insurance, engineers, protection execs and anxious corporation administration will purchase this ebook to capitalize at the author's life-long expertise.

Radionuclides in the Environment: Influence of chemical speciation and plant uptake on radionuclide migration

This booklet offers large and complete info to researchers and academicians who're drawn to radionuclide illness, its resources and environmental impression. it's also priceless for graduate and undergraduate scholars focusing on radioactive-waste disposal and its effect on usual in addition to artifical environments.

Extra resources for Chemical Reactions in Solvents and Melts

Sample text

V (2 - x) 7 9 j j (1957)]. 2a CRS 42 CHEMICAL REACTIONS IN SOLVENTS AND MELTS Solvent pH i 6 , Solvent 7 8 - ^^/ 9 n 10 jr 11 12 13 - j S ^ ^ ml HCI FIGS. 22-24. Werner, / . Am. Chem. Soc. 50, 2367 (1928)]. The pH of half-neutralization depends on the nature of the titrating acid; the pH for a given excess of titrant depends onlthe nature of titrated base. 3. Titration of weak bases by a weak acid (or inversely): see the case where the solvent does not interact. 4. Titration of a metallic salt MA by an acid HA'.

It is the same for aliphatic amines and substituted pyridines. It is impossible at present to relate the two phenomena. Effect of Association due to Hydrogen Bonding on Acid-Base Reactions We are, most of all, interested to know how hydrogen bonds can affect acid-base reactions and how to take them into account. We suppose that B and HA, when placed together, react according to an acid-base reaction. If the reacting species are associated by hydrogen bonding, their reactivity with respect to proton transfer is modified.

CALDIN, Quart. Revs. 7, 255 (1953). COULSON, Research (London) 10, 149 (1957). MCCLELLAN, (a) The Hydrogen Bond, Freeman, 1960 (2250 references). (b) Effect of condensation and of association by hydrogen bonding on acid-base reactions. 5. HARTLEY, / . Chem. Soc. 199 (1931). 6. WALDEN and E. BIRR, Z. Physik. Chem. A163, 263, 321 (1932). 7. V . K . DOWNES, / . Am. Chem. Soc. 55, 1840 (1933). 8. HETZER, / . Res. Nat. Bur. Stand. 46, 496 (1951). 9. SINGLETERRY, / . Phys. Chem. 56, 604 (1952). 10. , / .

Download PDF sample

Rated 4.34 of 5 – based on 17 votes