By Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez
The sphere of CMA (complex macromolecular structure) stands on the leading edge of fabrics technological know-how, and has been a locus of extreme examine job lately. This ebook provides an intensive description of the synthesis, characterization, and self-assembly of recently-developed complicated architectural fabrics with a couple of capability functions.
The architectural polymers, together with bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are brought bankruptcy through bankruptcy within the e-book. specifically, the e-book additionally emphasizes the subject of artificial breakthroughs through living/controlled polymerization considering that 2000.
additionally, well known authors give a contribution on unique issues reminiscent of helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, that have attracted massive curiosity as novel polymer fabrics with capability destiny purposes. furthermore, contemporary advances in reactive mixing completed with well-defined end-functionalized polymers are mentioned from an commercial viewpoint. subject matters on polymer-based nanotechnologies, together with self-assembled architectures and suprastructures, nano-structured fabrics and units, nanofabrication, floor nanostructures, and their AFM imaging research of hetero-phased polymers also are incorporated.
Provides finished insurance of lately constructed complicated architectural materialsContent:
Chapter 1 Cyclic and Multicyclic Topological Polymers (pages 1–19): Takuya Yamamoto and Yasuyuki Tezuka
Chapter 2 Ultrarapid ways to gentle Macromolecular Conjugation (pages 21–52): Andrew J. Inglis and Christopher Barner?Kowollik
Chapter three Synthesis and Self?Assembly of Hydrogen?Bonded Supramolecular Polymers (pages 53–95): Wolfgang H. Binder, Claudia Enders, Florian Herbst and Katharina Hackethal
Chapter four fresh artificial advancements in Miktoarm superstar Polymers with greater than 3 diversified hands (pages 97–132): Akira Hirao, Mayumi Hayashi, Tomoya Higashihara and Nikos Hadjichristidis
Chapter five specific Synthesis of Dendrimer?Like Star?Branched Polymers, a brand new classification of Well?Defined Hyperbranched Polymers (pages 133–167): Hee?Soo Yoo and Akira Hirao
Chapter 6 Arborescent Polymers with a Mesoscopic Scale (pages 169–194): Toufic Nabil Aridi and Mario Gauthier
Chapter 7 Hyperbranched Glyco?Conjugated Polymers (pages 195–227): Toshifumi Satoh and Toyoji Kakuchi
Chapter eight hugely Branched sensible Polymer Architectures by way of Click?Chemistry thoughts (pages 229–265): Mieke Lammens and Filip Du Prez
Chapter nine dwelling Alkene Polymerization for Polyolefin Architectures (pages 267–316): Amelia M. Anderson?Wile, Joseph B. Edson and Geoffrey W. Coates
Chapter 10 Precision Polyolefins (pages 317–347): Erik B. Berda and Kenneth B. Wagener
Chapter eleven Polyhomologation: The dwelling Polymerization of Ylides (pages 349–376): Jun Luo and Kenneth J. Shea
Chapter 12 Phenylenevinylene Homopolymers and Block Copolymers through Ring?Opening Metathesis Polymerization (pages 377–393): Chin?Yang Yu and Michael L. Turner
Chapter thirteen Block Copolymers Containing Rod Segments (pages 395–429): Tomoya Higashihara and Mitsuru Ueda
Chapter 14 Synthesis of Well?Defined Poly(meth)acrylamides with diversified Stereoregularity by means of dwelling Anionic Polymerization (pages 431–460): Takashi Ishizone
Chapter 15 advanced Macromolecular Chimeras (pages 461–489): Hermis Iatrou, Marinos Pitsikalis, Georgios Sakellariou and Nikos Hadjichristidis
Chapter sixteen Self?Assembly and purposes of Polyferrocenylsilane Block Copolymers (pages 491–526): George R. Whittell, Jessica Gwyther, David A. Rider and Ian Manners
Chapter 17 practical Polymeric Nanostructures ready through Self?Assembly and past (pages 527–567): Rachel ok. O'Reilly
Chapter 18 Morphologies of Block and Star?Branched Polymers with 3 parts (pages 569–591): Hirokazu Hasegawa
Chapter 19 Morphologies and Photophysical houses of Conjugated Rod–Coil Block Copolymers (pages 593–622): Chi?Ching Kuo, Cheng?Liang Liu and Wen?Chang Chen
Chapter 20 Bulk Self?Assembly of Linear Hybrid Polypeptide?Based Diblock and Triblock Copolymers (pages 623–645): Sebastien Lecommandoux
Chapter 21 AFM examine of Comb (Co)Polymers with advanced Chain structure (pages 647–683): Michel Schappacher and Alain Deffieux
Chapter 22 Tunable Thermoresponsive Polymers through Molecular layout (pages 685–715): Richard Hoogenboom
Chapter 23 Fluorine?Containing Block Copolymers: Synthesis and alertness as a Template for Nanocellular and Porous buildings utilizing Supercritical Carbon Dioxide (pages 717–737): Hideaki Yokoyama and Kenji Sugiyama
Chapter 24 Architectural Polymers, Nanostructures, and Hierarchical constructions from Block Copolymers (pages 739–761): Ian Wyman and Guojun Liu
Chapter 25 Block Copolymer Nanostructured skinny movies for complicated Patterning (pages 763–790): Michelle A. Chavis, Evan L. Schwartz and Christopher ok. Ober
Chapter 26 Ring Polymers: potent Isolation and certain houses (pages 791–821): Haskell W. Beckham
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Additional resources for Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly
Barner-Kowollik, “Ultra rapid approaches to mild macromolecular conjugation,” Macromolecular Rapid Communications, 2010, 31, 14, 1247–1266. Ó Wiley-VCH Verlag GmbH & Co. , 2004; Lowe, 2010). , 2008; Bertin and Schlaad, 2009). Within this context, there are two main modes in which the thiol-ene reaction may be applied: the ionic mechanism or the radical mechanism. The ionic mechanism is taken to represent the various methods of performing Michael-type additions of the thiol moieties to an alkene, whereas the radical mechanism is taken to encompass the ways in which thiyl radicals are generated and add across the double bond of the alkene.
2007). 12) (Tezuka and Ohashi, 2005). , 2003b). 12 Synthesis of manacle- and y-shaped topological polymeric isomers through the double metathesis of an H-shaped prepolymer (Tezuka and Ohashi, 2005). 13 Synthesis of a d-graph polymer from an 8-shaped prepolymer having two allyl groups (Tezuka and Fujiyama, 2005). Moreover, a dicyclic 8-shaped polymer precursor having two allyl groups at the opposite positions of the two ring units has been produced through the ESA-CF process by using a linear telechelic precursor having an allyl group at the center position and having cyclic ammonium salt end groups.
In the case of RAFT-HDA chemistry, it was found that dithioesters bearing an EWG on the thiocarbonyl moiety not only may be effectively used as controlling agents in RAFT polymerization, but also serve as highly efficient dienophiles in [4 þ 2] cycloadditions. 3. , 2008). In these cases, depending upon the structure of the dienophile, quantitative conversions into the targeted products were achieved at 50 C within a 2–24 h timeframe. Importantly, and unlike some other reactions that have been touted as macromolecular click conjugations, the above systems all proved to be highly efficient (by macromolecular standards) by using 1 : 1 stoichiometry between the respective reactants, a characteristic that becomes highly useful when purification of the click products become problematic.